SIZE EXCLUSION CHROMATOGRAPHY AND NUCLEAR MAGNETIC RESONANCE TECHNIQUES FOR PREDICTING ASPHALT YIELDS AND VISCOSITIES FROM CRUDE OILANALYSES

Auteur(s)
BEAZLEY, PM MARATHON OIL CO, USA HAWSEY, LE MARATHON OIL CO, USA PLUMMER, MA MARATHON OIL CO, USA
Jaar
Samenvatting

Size exclusion chromatography (SEC) and nuclear magnetic resonance (NMR) techniques for predicting asphalt yield and viscosity as functions of crude oil type and manufacturing conditions are detailed in this paper. SEC conditions were varied to yield crude oil component distributions to the asphalt phase that agreed with the thermodynamic requirements for distillation processes. Silanized-silica column packing and ultraviolet detection yielded better results than polystyrene packing and refractive index detection. Relatively standard NMR conditions were used to determine the ratio of aromatic protons to paraffinic protons. This ratio was used as a measure of the relative polarity of crude oil and asphalt components.(A).

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Publicatie

Bibliotheeknummer
I 829331 IRRD 9006
Uitgave

TRANSPORTATION RESEARCH RECORD TRANSPORTATION RESEARCH BOARD WASHINGTON DC USA 0361-1981 V0-309-04460-3 SERIAL 1987 1115 PAG:46-50 T8

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